| Description |
1 online resource. |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Note |
Includes index. |
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Online resource; title from title details screen (ScienceDirect, viewed November 24, 2015). |
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Print version record. |
| Contents |
Front Cover; ADVISORY BOARD; Advances in Physical Organic Chemistry; Copyright; CONTENTS; CONTRIBUTORS; PREFACE; One -- Metal Ion-Promoted Leaving Group Assistance in the Light Alcohols; 1. INTRODUCTION; 1.1 Problems with Water as a Solvent for Metal Ion-Promoted Solvolyses are Ameliorated in Alcohols; 2. METAL ION-PROMOTED LGA; 2.1 Brief Description of LGA and Modes of Involvement of the Metal Ion; 2.2 Early Examples with Acetyl Imidazole and Its (NH3)5CoIII-Complex where the Metal Ions Act as Lewis Activators and Provide L ... |
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2.3 Early Examples with Esters Having Complex Mechanisms for Methanolysis Promoted by Lanthanides and a Triazacyclododecane:ZnI ...2.4 DFT Computational Study of the Methanolysis of Carboxylate Esters Promoted by ZnII-Complexed Methoxide (18); 3. METAL ION-PROMOTED ALCOHOLYSIS OF PHOSPHATES; 3.1 Proof of Concept: LGA Provided by a CuII:Phenanthroline in the Solvolysis of Closely Positioned tri-, di-, and Monophosphates; 3.2 Bimolecular Catalytic Phosphate Cleavage Reactions where Metal Ion-Promoted LGA is Apparent; 3.3 DFT Computational Study of the 23-Promoted Methanolytic Cleavage of 24f |
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5. CONCLUSIONS AND SPECULATIONSACKNOWLEDGMENTS; REFERENCES; Two -- Medium Effects in Biologically Related Catalysis; 1. INTRODUCTION; 2. PHOSPHORYL TRANSFER REACTIONS; 2.1 Overview of Phosphoryl Transfer in Aqueous Solution; 2.2 Solvent Effects in Phosphoryl Transfer Reactions; 2.3 Surfactants Effects on Phosphoryl Transfer Reactions; 3. SOLVENT EFFECTS IN SULFURYL TRANSFER REACTIONS; 4. SOLVENT EFFECTS IN SN2 REACTIONS OF S-ADENOSYLMETHIONINE; 5. DECARBOXYLATION REACTIONS; 5.1 Decarboxylation of Orotic Acid Derivatives; 5.2 Decarboxylation of 3-Carboxybenzisoxazoles (Kemp Decarboxylation) |
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6. KEMP ELIMINATION7. CONCLUSIONS AND IMPLICATIONS FOR BIOINSPIRED CATALYSIS; ACKNOWLEDGMENTS; REFERENCES; Three -- Combustion Pathways of Biofuel Model Compounds: A Review of Recent Research and Current Challenges Pertaini ...; 1. INTRODUCTION; 1.1 Kinetic Mechanisms; 1.2 Experimental Techniques; 1.3 Computational Techniques; 1.4 Simplifying Detailed Mechanisms; 1.5 High- and Low-Temperature Oxidation Pathways; 1.6 Atmospheric Chemistry; 2. OVERVIEW OF FIRST-GENERATION BIOFUELS AND THEIR MODEL COMPOUNDS; 2.1 Combustion Pathways of Ethanol; 2.1.1 Unimolecular Decomposition of Ethanol |
| Summary |
Advances in Physical Organic Chemistry series of volumes is the definitive resource for authoritative reviews of work in physical organic chemistry. It aims to provide a valuable source of information not only for physical organic chemists applying their expertise to both novel and traditional problems but also for non-specialists across diverse areas who identify a physical organic component in their approach to research. Its hallmark is quantitative, molecular level understanding of phenomena across a diverse range of disciplines. Reviews the application of quantitative and mathematical methods to help readers understand chemical problems Provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry Covers organic, organometallic, bioorganic, enzymes, and materials topics The only regularly published resource for reviews in physical organic chemistry Chapters are written by authoritative experts Wide coverage of topics requiring a quantitative, molecular-level understanding of phenomena across a diverse range of disciplines. |
| Subject |
Physical organic chemistry.
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Chimie organique physique.
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SCIENCE -- Chemistry -- Organic.
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Physical organic chemistry
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| Added Author |
Williams, Ian H., editor.
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Williams, Nicholas H., editor.
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| ISBN |
9780128024294 (electronic bk.) |
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0128024291 (electronic bk.) |
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9780128022283 |
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0128022280 |
| Standard No. |
GBVCP 879386150 |
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AU@ 000057007106 |
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AU@ 000056916094 |
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