| Description |
1 online resource. |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Series |
Advances in Inorganic Chemistry ; volume 83
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Advances in inorganic chemistry ; volume 83.
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| Note |
Includes index. |
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Online resource; title from PDF title page (ScienceDirect, viewed July 1, 2024). |
| Contents |
Frot Cover -- Series Page -- Advances in Inorganic Chemistry -- Copyright -- Contents -- Contributors -- Preface -- References -- Chapter One: Photophysical properties of copper(I), zinc(II) and nickel(II) complexes -- 1 Introduction -- 2 Copper(I) complexes -- 2.1 Mononuclear copper(I) complexes -- 2.2 Polynuclear copper(I) complexes -- 3 Zinc(II) complexes -- 4 Nickel(II) complexes -- 5 Concluding remarks -- Acknowledgements -- References -- Chapter Two: Chromic behaviors and color control of luminescent copper(I) complexes -- 1 Introduction -- 2 Diversity of structures and luminescence states of Cu(I) complexes -- 3 Structural transformation and chromic behaviors of Cu(I) complexes in the solid state -- 4 Vapochromic luminescence in mononuclear and dinuclear copper(I) complexes -- 5 Vapochromic luminescence of coordination polymers -- 6 Summary and future prospect -- Acknowledgment -- References -- Chapter Three: Ligand-to-metal charge-transfer states in emissive d0 metallocenes: Design strategies for titanocene based photocatalystsLigand-to-metal charge-transfer states -- 1 Introduction -- 1.1 Background -- 1.2 Photophysical processes leading to excited-state deactivation -- 1.3 Strategies for increasing excited-state lifetimes of TM complexes -- 2 Photoactive complexes of d0 transition metals -- 2.1 Non-metallocene complexes -- 2.2 Metallocenes -- 2.2.1 Frontier orbitals of metallocenes -- 2.2.2 Cp⁎2ScCl -- The first example of emission from a LMCT state -- 2.2.3 Tantalocenes -- 2.2.4 Zirconocenes and hafnocenes -- 2.2.4.1 Zirconocenes and hafnocenes with thiolate ligands -- 2.2.4.2 A structurally rigid zirconocene -- 2.2.4.3 Polyphenyl zirconocene and hafnocene -- 2.2.4.4 Zirconocenes and hafnocenes with pendant donor groups -- 2.3 Lessons Learned -- 3 Photoactive Cp2TiX2 (X = halide, SCN) titanocenes -- 3.1 Photophysics. |
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3.2 Photocatalysis using Cp2TiCl2 -- 4 Donor substituted ethynyltitanocenes -- 4.1 Scope and synthesis -- 4.2 Titanocenes with ethynylferrocene donor ligands -- 4.2.1 Characterization of the MMCT state -- 4.2.2 The role of MC states on MMCT-state relaxation -- 4.2.3 Solvatochromism -- 4.3 Titanocenes with arylethynyl donor ligands -- 4.3.1 Characterization of the LMCT state -- 4.3.2 Photochemical decomposition -- 4.4 Arylethynyltitanocenes with d10 metals coordinated between the alkynes -- 4.4.1 Characterization of the CT states -- 4.4.2 Investigating the mechanism for improved photostability -- 4.4.3 Investigating the mechanism for photophysical nonradiative decay -- 4.4.4 An emissive titanocene with the Cp⁎ ligand -- 5 Design considerations for titanocene photocatalysts -- 6 Summary -- Acknowledgments -- References -- Chapter Four: The photophysics and applications of molecular rubiesThe photophysics and applications of molecular rubies -- 1 Introduction -- 2 Excited state properties of Molecular Rubies -- 2.1 Ground state absorption -- 2.2 Photoluminescence properties -- 2.3 Tuning of spin-flip energies -- 2.4 Excited state distortion -- 2.5 Ultrafast excited state dynamics -- 2.6 Radiative and non-radiative deactivation of spin-flip states -- 3 Applications -- 3.1 Optical sensing with Molecular Rubies -- 3.2 Molecular Rubies in photoinduced energy transfer and photoredox catalysis -- 3.3 Molecular Rubies in photon upconversion -- 3.4 Circularly polarized luminescence of Molecular Rubies -- 3.5 Other applications of Molecular Rubies -- 4 Conclusion -- Acknowledgments -- Supplementary material -- References -- Chapter Five: Photoactive MOFs for CO2 activation utilizing earth abundant metals -- 1 Introduction -- 2 Benchmarking -- 3 Node based catalysts -- 4 Linker-based catalysts -- 5 Pore guest catalysts -- 6 MOF composites -- 7 Conclusion. |
| Subject |
Transition metals.
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Photochemistry.
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Métaux de transition.
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Photochimie.
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| Added Author |
Eldik, Rudi van, editor.
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Ford, Peter C., editor.
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| ISBN |
9780443237461 |
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