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Title Conjugated polymer synthesis : methods and reactions / edited by Yoshiki Chujo.

Imprint Weinheim : Wiley-VCH ; Chichester : John Wiley [distributor], 2010.

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Location Call No. OPAC Message Status
 Axe 2nd Floor Stacks  547.70457 C761 2010    ---  Available
Description 313 p. : ill. ; 25 cm.
Bibliography Includes bibliographical references and index.
Summary Edited and authored by top international experts, this first book on conjugated polymers with a focus on synthesis provides a detailed overview of all modern synthetic methods for these highly interesting compounds.
Contents Machine generated contents note: 1. Organometallic Polycondensation for Conjugated Polymers / Takakazu Yamamoto -- 1.1. Basic Organometallic C-C Coupling -- 1.2. Syntheses of π-Conjugated Polymers -- 1.3. Optical Properties -- 1.3.1. UV-Vis Data -- 1.3.2. Photoluminescence -- 1.3.3. Other Optical Properties -- 1.4. Redox Behavior and Electrical Conductivity -- 1.5. Linear Structure and Alignment on the Surface of Substrates -- 1.6. Stacking in the Solid and Colloid -- 1.7. Chemical Reactivity and Catalysis -- 1.7.1. Metal Complexes and Modification of Nitrogen -- 1.8. Electronic and Optical Devices (ECD, Battery, EL, Diode, Transistor, Nonlinear Optical Device, etc.) -- 1.8.1. Redox Functions -- 1.8.2. Electronic and Optical Devices -- 1.9. Conclusions -- References -- 2. Catalyst-Transfer Condensation Polymerization for Precision Synthesis of [pi]-Conjugated Polymers / Tsutomu Yokozawa -- 2.1. Introduction -- 2.2. Kumada-Tamao Coupling Polymerization with Ni Catalyst
2.2.1. Polythiophene -- 2.2.1.1. Discovery and Mechanism of Catalyst-Transfer Condensation Polymerization -- 2.2.1.2. A Variety of Monomers -- 2.2.1.3. Block Polythiophenes -- 2.2.1.4. Block Copolymers of Polythiophene and Other Polymers -- 2.2.1.5. Graft Copolymers -- 2.2.2. Polyphenylenes -- 2.2.3. Polypyrroles -- 2.2.4. Polyfluorenes and Polycarbazoles -- 2.3. Suzuki-Miyaura Coupling Polymerization with Pd Catalyst -- 2.3.1. Polyfluorenes -- 2.3.2. Polyphenylenes -- 2.4. Conclusion -- References -- 3. Regioregular and Regiosymmetric Polythiophenes / Richard D. McCullough -- 3.1. Introduction -- 3.2. Synthesis of Polythiophene and Regioirregular Polythiophenes -- 3.3. Head-to-Tail Coupled Regioregular Poly(3-Alkylthiophene)s -- 3.3.1. Design and Synthesis of rrP3ATs -- 3.3.1.1. McCullough Method -- 3.3.1.2. Rieke Method -- 3.3.1.3. GRIM Method -- 3.3.1.4. Palladium-Catalyzed Polymerization Methods -- 3.3.2. Mechanism of the Nickel-Catalyzed Polymerization -- 3.4. Side Chain Functionalized HT Regioregular Polythiophenes
3.4.1. Heteroatom-Containing Groups -- 3.4.2. Aromatic-Containing Group -- 3.4.3. Chiral Groups -- 3.4.4. [gamma]-Functionalized Groups -- 3.5. End Group Functionalized HT Regioregular Polythiophenes -- 3.5.1. Postpolymerization End Group Functionalization -- 3.5.2. In Situ End Group Functionalization -- 3.6. Block Copolymers Derived from HT Regioregular Polythiophenes -- 3.6.1. All-Conjugated Block Copolymers -- 3.6.2. Conjugated-Non-Conjugated Block Copolymers -- 3.7. Universal Use of the GRIM Method -- 3.8. Regiosymmetric Polythiophenes -- 3.9. Summary -- References -- 4. Functional Hyperbranched Polymers Constructed from Acetylenic An-Type Building Blocks / Ben Zhong Tang -- 4.1. Introduction -- 4.2. Hyperbranched Polymers Constructed from Acetylenic An-Type Building Blocks -- 4.2.1. Hyperbranched Poly(Alkylenephenylene)s (hb-PAPs) -- 4.2.1.1. Synthesis -- 4.2.1.2. Structures -- 4.2.1.3. Properties -- 4.2.2. Hyperbranched Poly(Arylenephenylene)s (hb-PArPs) -- 4.2.2.1. Synthesis
4.2.2.2. Structures -- 4.2.2.3. Properties -- 4.2.3. Hyperbranched Poly(Aroylphenylene)s (hb-PAkPs) and Poly(Aroxycarbonylphenylene)s (hb-PAePs) -- 4.2.3.1. Synthesis -- 4.2.3.2. Structures -- 4.2.3.3. Properties -- 4.2.4. Hyperbranched Polytriazoles (hb-PTAs) -- 4.2.4.1. Synthesis -- 4.2.4.2. Structures -- 4.2.4.3. Properties -- 4.2.5. Hyperbranched Poly(Aryleneethynylene)s (hb-PAEs) -- 4.2.5.1. Synthesis -- 4.2.5.2. Properties -- 4.2.6. Hyperbranched Polydiynes (hb-PDYs) -- 4.2.6.1. Synthesis -- 4.2.6.2. Thermal Curing -- 4.2.6.3. Micropattern Formation -- 4.2.6.4. Metal Complexation -- 4.2.6.5. Magnetic Ceramization -- 4.3. Conclusions -- References -- 5. Through-Space Conjugated Polymers / Yoshiki Chujo -- 5.1. Introduction -- 5.2. Through-Space Conjugated Polymers with the Layered [pi]-Electron Systems in the Side Chain -- 5.2.1. Polyacenaphthylene -- 5.2.2. Polydibenzofulvene -- 5.2.3. Polybenzofulvene -- 5.2.4. Polystyrene-graft-Poly(4-Phenylquinoline) -- 5.2.5. [3.2]Paracyclophane-Containing Polymer
5.2.6. Polymethylene with [2.2]Paracyclophane -- 5.3. Through-Space Conjugated Polymers with the Layered [pi]-Electron Systems in the Main Chain -- 5.3.1. Phenylene-Layered Polymer Based on a Norbornane Scaffold -- 5.3.2. Aromatic Ring-Layered Polymers Based on a Xanthene Scaffold -- 5.3.2.1. [2.2]Paracyclophane-Layered Polymer -- 5.3.2.2. Oligophenylene-Layered Polymers -- 5.3.2.3. Ferrocene-Layered Polymers Based on a Naphthalene Scaffold -- 5.3.3. Cyclophane-Containing Through-Space Conjugated Polymers -- 5.3.3.1. [2.2]Metacyclophane-Containing Through-Space Conjugated Polymers -- 5.3.3.2. [2.2]Paracyclophane-Containing Through-Space Conjugated Polymers -- 5.4. Conclusion -- References -- 6. Fully Conjugated Nano-Sized Macrocycles: Syntheses and Versatile Properties / Masahiko Iyoda -- 6.1.Introduction -- 6.2. Synthesis of [pi]-Conjugated Macrocycles -- 6.2.1. One-Pot Synthesis of Phenylacetylene Macrocycles -- 6.2.2. Template Synthesis of Macrocycles -- 6.2.3. Synthesis of Conjugated Thiophene, Porphyrin, and Heteroarylene Macrocycles
6.3. Isolation and Self-Association in Solution and in the Solid State -- 6.4. Versatile Properties of Giant [pi]-Conjugated Macrocycles -- 6.5. Conclusion -- References -- 7. Organoboron Conjugated Polymers / Yoshiki Chujo -- 7.1. Introduction -- 7.2. Tricoordinate Boron [pi]-Conjugated Polymers -- 7.2.1. Hydroboration Polymerization of Diyne Monomers -- 7.2.2. Tin-Boron Exchange Polymerization of Bis(Trimethylsilyl) Monomer -- 7.2.3. Haloboration-Phenylboration Polymerization of Diyne Monomers -- 7.2.4. Polycondensation of Aryldimethoxyborane Using Grignard and Organolithium Reagents -- 7.2.5. Stepwise Reaction from Boraanthracene -- 7.3. Tetracoordinate Boron [pi]-Conjugated Polymers -- 7.3.1. [pi]-Conjugated Poly(Cyclodiborazane)s -- 7.3.2. Poly(Pyrazabole)s -- 7.3.3. [pi]-Conjugated Organoboron Quinolate Polymers -- 7.3.4. [pi]-Conjugated Organoboron Diketonate Polymer -- 7.3.5. [pi]-Conjugated BODIPY-Based Polymers -- 7.4. [pi]-Conjugated Carborane-Based Polymers -- 7.5. Conclusions -- References
8. Recent Developments in [pi]-Conjugated Macromolecules with Phosphorus Atoms in the Main Chain / Derek P. Gates -- 8.1. Introduction -- 8.2. Poly(Phosphole) and Related Polymers -- 8.3. Poly(p-Phenylenephosphine) and Related Polymers -- 8.4. Poly(Vinylenephosphine)s and Related Polymers -- 8.5. Poly(p-Phenylenephosphaalkene)s and Related Polymers -- 8.6. Poly(p-Phenylenediphosphene)s and Related Polymers -- 8.7. Summary -- References -- 9. Organo-Arsenic, Phosphorus, and Antimony Conjugated Polymers / Yoshiki Chujo -- 9.1. Introduction -- 9.2. Survey of Group 15 Element-Containing Polymers -- 9.3. Carbon-Main Group Element Bond Formation Via Bismetallation -- 9.4. Homocyclic Compounds of Group 15 Elements -- 9.5. Poly(Vinylene-Arsine)s -- 9.6. Poly(Vinylene-Phosphine)s -- 9.7. Poly(Vinylene-Stibine)s -- 9.8. Periodic Terpolymerization of Cyclooligoarsine, Cyclooligostibine, and an Acetylenic Compound -- 9.9. Stability -- 9.10. Optical Properties -- 9.11. Coordination Ability of Poly(Vinylene-Arsine)s Towards Transition Metal Ions
9.12. Cross-Linked Poly(Vinylene-Arsine)s -- 9.13. Conclusion -- References -- 10. Synthetic Strategies to Conjugated Main-Chain Metallopolymers / Ulrich S. Schubert -- 10.1. Introduction -- 10.2. [pi]-Conjugated Polymers with Terpyridine Units and Other Tridentate Ligands as Part of the Main Chain -- 10.3. [pi]-Conjugated Polymers with Porphyrin Units as Part of the Main Chain -- 10.4. Rigid-Rod Polymetallaynes -- 10.5. Conclusion and Outlook -- References -- 11. Helical Polyacetylene Prepared in a Liquid Crystal Field / Kazuo Akagi -- 11.1. Introduction -- 11.2. Chiral Dopants and Chiral Nematic LCs -- 11.3. Acetylene Polymerization in Chiral Nematic LC -- 11.4. Characterization of Helical Polyacetylene Film -- 11.5. Summary -- References.
Subject Conjugated polymers.
Added Author Chujo, Y. (Yoshiki)
ISBN 9783527322671 (hbk.)
3527322671 (hbk.)
Standard No. AU@ 000046557162

 
    
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