4.3. Transport properties -- 4.4. Applications of supercritical fluids -- References -- Chapter 5: Thermodynamics and transport properties of mixtures composed of metal complexes and supercritical fluids -- 5.1. Introduction -- 5.2. Phase behavior -- 5.3. Solubility and binary diffusion coefficients of metal complexes in SCF -- 5.4. Determination of high-pressure phase behavior data -- 5.5. Experimental procedure -- 5.6. Modeling solubility of metal complexes in SCFs -- 5.7. Experimental determination and modeling of the solubility of salts in sub and supercritical H2O -- References
Chapter 6: Thermodynamics and kinetics of adsorption of metal complexes on surfaces from supercritical solutions -- 6.1. Adsorption -- 6.1.1. Physisorption -- 6.1.2. Chemisorption -- 6.2. Adsorption isotherms -- 6.2.1. Adsorption isotherm models -- 6.2.1.1. The Langmuir model -- 6.2.1.2. The Freundlich model -- 6.3. Adsorption of supercritical fluids -- 6.4. Adsorption of solutes from supercritical mixtures -- 6.5. Adsorption of metal complexes on surfaces -- 6.5.1. Experimental techniques for determination of adsorption isotherms -- 6.5.1.1. Batch adsorption
6.5.1.2. Frontal analysis chromatography -- 6.5.2. Adsorption isotherms for metal complex-adsorbent-scCO2 systems -- 6.5.3. Kinetics of adsorption of metal complexes on porous substrates from supercritical solutions -- References -- Chapter 7: Synthesis of nanostructured composites of metals by supercritical deposition (SCD) -- 7.1. Supported nanoparticles on inorganic and carbon supports -- 7.2. Polymer supported nanoparticles -- 7.3. Supported bimetallic and multimetallic nanoparticles -- 7.4. Metallic films -- 7.5. Comparison with other methods -- References