| Description |
1 online resource |
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text txt rdacontent |
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still image sti rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Note |
Includes index. |
| Contents |
Front Cover -- Stereochemistry -- Copyright Page -- Contents -- About the authors -- Foreword -- Preface -- I. Fundamentals of stereochemistry -- 1 Basic concepts of structure and stereochemistry -- 1.1 Introduction -- 1.2 A brief history -- 1.3 Molecular geometry -- 1.3.1 Van der Waals' radius -- 1.3.2 Bond length -- 1.3.3 Bond angle -- 1.3.4 Dihedral angle -- 1.4 Isomers -- 1.4.1 Conformational isomers -- 1.4.2 Configuration and configurational isomers -- 1.5 Projection formulae -- 1.5.1 Fischer projection -- 1.5.2 Newman projection -- 1.5.3 Sawhorse projection |
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Questions and Problems -- References -- 3 Elements of chirality and chiral stereoisomerism -- 3.1 Introduction -- 3.2 Molecules with central chirality -- 3.2.1 Configurational descriptors for molecules with central chirality -- 3.2.1.1 The D-L system -- 3.2.1.2 The R/S system -- 3.3 Molecules with two or more chiral centres -- 3.3.1 Constitutionally unsymmetrical chiral molecules -- 3.3.1.1 Erythro and Threo -- 3.3.1.2 Pref and Parf -- 3.3.1.3 Like (l) and unlike (u) -- 3.3.1.4 Anti and Syn notations -- 3.3.1.5 Brewster's system |
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3.3.2 Stereoisomerism in constitutionally symmetrical chiral molecules -- 3.3.3 Stereoisomerism in cyclic molecules -- 3.4 Molecules with the presence of chiral axis -- 3.4.1 Assignment of configurational descriptors to molecules with presence of chiral axis -- 3.4.2 Allenes -- 3.4.3 Alkylidene cycloalkanes/Hemispiranes -- 3.4.4 Spiranes -- 3.4.5 Atropisomerism -- 3.4.6 Atropisomerism of biaryls, restricted rotation around sp2-sp2, C-C bond -- 3.4.7 Assignment of configurational descriptors to chiral biphenyls -- 3.4.8 Bridged biphenyls -- 3.5 Planar Chirality |
| Subject |
Stereochemistry.
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Stéréochimie.
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Stereochemistry
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| Added Author |
Hasan, Mohammed.
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| Other Form: |
Print version: 0128210621 9780128210628 (OCoLC)1237102163 |
| ISBN |
9780128210635 (electronic bk.) |
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012821063X (electronic bk.) |
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9780128210628 |
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0128210621 |
| Standard No. |
AU@ 000069686197 |
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UKMGB 020202624 |
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AU@ 000069791638 |
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