| Edition |
First edition. |
| Description |
1 online resource |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Series |
Latest trends in palladium chemistry |
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Latest trends in palladium chemistry.
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| Note |
Online resource; title from PDF title page (EBSCO, viewed June 20, 2019) |
| Summary |
Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered. Palladacycles: Catalysis and Beyond reveals the tremendous advances that have taken place in the potential applications of palladacycles as versatile catalysts in academia and industry. It is a valuable resource for synthetic chemists, organometallic chemists, and chemical biologists. |
| Contents |
Front Cover; Palladacycles: Catalysis And Beyond; Copyright; Contents; Contributors; Chapter 1: Palladacycles as Efficient Precatalysts for Suzuki-Miyaura Cross-Coupling Reactions; 1. Introduction; 2. Imine and Amine Palladacycles; 3. Oxime Palladacycles; 4. Ferrocene Palladacycles; 5. Pincer Palladacycles; 6. Phosphorus Donor Atom Palladacycles; 7. Carbene Palladacycles; 8. Alternative Palladacycles; 9. Conclusions; References; Chapter 2: Palladacycles as Precatalysts for Heck and Sonogashira Cross-Coupling Reactions; 1. Introduction; 2. Phosphine-Based Palladacycles |
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2.1. Heck Cross-Coupling Reaction2.1.1. Herrmann-Beller-Type Palladacycles; 2.1.2. Other Dimeric and Monomeric Phosphapalladacycles; 2.1.3. Diphosphine-Palladacycles; 2.2. Sonogashira Cross-Coupling Reaction; 3. Ferrocene-Based Palladacycles; 3.1. Heck Cross-Coupling Reaction; 3.1.1. Ferrocene-Based Palladacycles With N(sp3) Atom; 3.1.2. Ferrocene-Based Palladacycles With N(sp2) Atom; 3.1.2.1. Imine-Derived Ferrocenyl Palladacycles; 2.1.2.2. Oxime-Derived Ferrocenyl Palladacycles; 3.1.3. Other Ferrocenyl Palladacycles; 3.2. Sonogashira Cross-Coupling Reaction |
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4. Amine/Imine/Oxime-Based Palladacycles4.1. Heck Cross-Coupling Reaction; 4.1.1. Amine-Based Palladacycles; 4.1.2. Imine-Based Palladacycles; 4.1.3. Oxime-Based Palladayclces; 4.1.4. N-Heterocycles C, N or C, N, N-Donor Palladacycles; 4.1.5. Other Nitrogen-Containing Palladacycles; 4.2. Sonogashira Cross-Coupling Reaction; 5. N-Heterocyclic Carbene-Based Palladacycles; 5.1. Heck Cross-Coupling Reaction; 5.1.1. Imidazol-2-ylidene NHC-Based Palladacycles; 5.1.2. Functionalized Imidazol-2-ylidene NHC-Based Palladacycles; 5.1.2.1. Pyridyl-Imidazol-2-ylidene NHC-Based Palladacycles |
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5.1.2.2. Other Imidazol-2-ylidene NHC-based palladacycles5.1.3. Benzimidazol-2-ylidene NHC-Based Palladacycles; 5.1.4. Other NHC-Based Palladacycles; 5.2. Sonogashira Cross-Coupling Reaction; 6. Pincer-Based Palladacycles; 6.1. Heck Cross-coupling Reaction; 6.1.1. PCP- and PNP-Pincer Palladacycles; 6.1.2. NCN- and CNC Pincer Palladacycles; 6.1.3. SCS-, SNS-, SeCSe- and SeNSe-Pincer Palladacycles; 6.1.4. CNN-Pincer Palladacycles; 6.1.5. LCL- and LNL-Pincer Palladacycles (L=C, N, or O; L=C, N, O, S, Se, P); 6.2. Sonogashira Cross-Coupling Reaction; 7. Other Palladacycles |
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7.1. Heck Cross-Coupling Reaction7.2. Sonogashira Cross-Coupling Reaction; 8. Conclusions and Prospects; References; Chapter 3: Palladacycles as Efficient Precatalysts for Negishi and Buchwald-Hartwig Amination Reactions; 1. Introduction; 1.1. Buchwald-Hartwig Amination: A Brief Historic Perspective; 1.2. General Features; 1.2.1. Mechanism; 1.2.2. Role of Ancillary Ligands; 1.2.3. Palladium Source; 2. Types of Palladacycles Used in Buchwald-Hartwig CN Bond Forming Reactions; 2.1. Group 1: Herrmann-Beller Palladacycle and Others Incorporating a CP Backbone |
| Bibliography |
Includes bibliographical references and index. |
| Subject |
Catalysis.
|
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Polycyclic compounds.
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Catalysis |
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Polycyclic Compounds |
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Catalyse.
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Composés polycycliques.
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SCIENCE -- Chemistry -- Organic.
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Catalysis
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Polycyclic compounds
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| Genre/Form |
Electronic books.
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| Added Author |
Maiti, Debabrata, author.
|
| Other Form: |
Print version : 9780128155059 |
| ISBN |
9780128165164 (electronic bk.) |
|
0128165162 (electronic bk.) |
|
9780128155059 (electronic bk.) |
|
0128155051 (electronic bk.) |
| Standard No. |
AU@ 000065403614 |
|
AU@ 000066136094 |
|
AU@ 000066781754 |
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UKMGB 019445465 |
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