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Title New materials for catalytic applications / edited by Vasile I. Parvulescu, Erhard Kemnitz.

Publication Info. Amsterdam : Elsevier, [2016]
©2016

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Location Call No. OPAC Message Status
 Axe Elsevier ScienceDirect Ebook  Electronic Book    ---  Available
Description 1 online resource : illustrations (some color)
text txt rdacontent
computer c rdamedia
online resource cr rdacarrier
text file rda
Note Online resource; title from PDF title page (Ebsco, viewed February 17, 2016).
Bibliography Includes bibliographical references and index.
Summary New Materials for Catalytic Applications proposes the use of both new and existing materials for catalytic applications, such as zeolites, metal oxides, microporous and mesoporous materials, and monocrystals. In addition, metal-oxides are discussed from a new perspective, i.e. nano- and photocatalytic applications. The material presents these concepts with a new focus on strategies in synthesis, synthesis based on a rational design, the correlation between basic properties/potential applications, and new catalytic solutions for acid-base, redox, hydrogenation, photocatalytic reactions, etc.
Contents Cover; Title Page; Copyright Page; Contents; List of Contributors; Chapter 1 -- Double Metal Cyanides as Heterogeneous Catalysts for Organic Reactions; 1 -- Introduction; 2 -- Epoxide Ring-Opening Reactions; 2.1 -- Ring-Opening Polymerization of Epoxides; 2.2 -- Copolymerization of CO2 and Epoxides; 2.3 -- Cycloaddition of CO2 to Epoxides; 2.4 -- Ring-Opening of Epoxides with Amines; 3 -- Esterification, Transesterification, and Hydrolysis Reactions; 3.1 -- Transesterification Reactions; 3.2 -- Esterification Reactions; 3.3 -- Hydrolysis Reactions; 3.4 -- Polyester Synthesis.
4 -- Addition and Coupling Reactions4.1 -- Hydroamination Reactions; 4.2 -- Aldol Condensation; 4.3 -- Prins Condensation; 5 -- Oxidation Reactions; 6 -- Conclusions; References; Chapter 2 -- Metal Organic Frameworks as Catalysts for Organic Reactions; 1 -- Introduction; 2 -- Stability Issues; 3 -- Zeolites Versus MOFs as Heterogeneous Catalysts; 4 -- Active Sites in MOFs; 5 -- MOFs for Oxidation Reactions; 6 -- C-C Coupling Reactions; 7 -- Hydrogenation Reactions; 8 -- Concluding Remarks; References; Chapter 3 -- On the Use of Organometallic Chemistry Concepts for the Synthesis of Nanocatalysts.
1 -- Introduction2 -- Methods for the Synthesis of Metal Nanoparticles and their Characterization; 2.1 -- Synthesis Tools to Produce Metal Nanoparticles; Organometallic complexes as the source of metal atoms; Ligands as stabilizers of metal nanoparticles; 2.2 -- Tools for the Characterization of Metal Nanoparticles; Quantification of hydrides at metal nanoparticle surface; Coordination of CO to probe the surface properties of metal nanoparticles; Catalysis to probe the surface state of metal nanoparticles; 3 -- Selected Examples of Metal Nanoparticle Synthesis and their Application in Catalysis.
3.1 -- In Organic MediaRhenium nanoparticles; Bimetallic nanoparticles; Phosphine and secondary phosphine oxide-stabilized Ru NPs for hydrogenation reactions; Carbene-stabilized nanoparticles for hydrogenation reactions; 3.2 -- Water-Soluble Nanoparticles for Hydrogenation Reactions in Aqueous Phase; 3.3 -- Supported Nanoparticles; Silica-supported nanoparticles for hydrogenation reactions; Carbon-supported nanoparticles for oxidation, C-C coupling, or hydrogenation reactions; 4 -- Conclusions and Outlook; Acknowledgments; References.
Chapter 4 -- Catalysts on Metallic Surfaces: Monoliths and Microreactors1 -- Overview; 2 -- The Metal Choice; 3 -- Catalyst Coating; 3.1 -- Metallic Substrate Pretreatment; 3.2 -- Catalyst Coating Methods; Coating methods in liquid phase; Washcoating; In situ growth/direct synthesis; Electrophoretic deposition; Electrochemical deposition; Electroless plating; Spray Coating; Coating methods in vapor phase; 4 -- Catalytic Layer: Influence of the Metallic Substrate and Deposition Procedure; 4.1 -- Influence of the Deposition Method; 4.2 -- Influence of the Metallic Substrate and the Reaction Conditions.
5 -- Transport Phenomena in Structured Catalysts.
Subject Catalysts.
Catalyseurs.
catalyst.
SCIENCE -- Chemistry -- Industrial & Technical.
TECHNOLOGY & ENGINEERING -- Chemical & Biochemical.
Catalysts
Added Author Pārvulescu, V. I. (Vasile I.), editor.
Kemnitz, Erhard, editor.
Other Form: Print version : 9780444635877
ISBN 9780444635884 (electronic bk.)
0444635882 (electronic bk.)
9780444635877
0444635874
Standard No. AU@ 000057218676
AU@ 000066076260
CHBIS 010796181
CHNEW 001013388
CHVBK 403943302
DEBSZ 482469021
GBVCP 870368966
GBVCP 87939160X
UKMGB 017711561

 
    
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