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1 online resource (1458 p.) |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Contents |
Front Cover -- Chemical Thermodynamics and Statistical Aspects -- Chemical Thermodynamics and Statistical Aspects -- Copyright -- Contents -- Preface -- I -- Chemical thermodynamics -- 1 -- Thermodynamics: principles and fundamentals -- Introduction -- 1.1 Principles and definitions -- 1.1.1 Thermodynamic systems and processes -- 1.1.2 Thermodynamic variables -- 1.1.3 Essential thermodynamic functions -- 1.2 Energy -- 1.2.1 Principles: definition, types, examples, and mathematic statement -- 1.2.2 Energy and chemical reactions: spontaneity, equilibrium, and estimation -- 1.3 Ideal gas -- 1.3.1 Definition -- 1.3.2 Properties -- 1.3.3 Avogadro's law -- 1.3.4 Boyle's law -- 1.3.5 Charles' law -- 1.3.6 Ideal gas law -- 1.4 State function -- 1.4.1 Principles: definition, examples, and significant -- 1.4.2 Mathematics: exact/inexact differentials and Euler's criterion for exactness -- 1.5 The kinetic theory for gases: assumption, definition, derivation, and temperature change -- 1.6 Real gas: properties and equations -- 1.6.1 Compression factor and virial coefficient -- 1.6.2 van der Waals equation -- 1.6.3 Principle of corresponding states -- 1.6.4 Reduced variables -- 1.7 Total and partial derivative expressions of temperature, pressure, and volume: expression for the finite change of thermody ... -- 1.7.1 Partial derivative expressions of temperature, pressure, and volume: expressions for the finite change of thermodynamic mai ... -- 1.8 Thermal equilibrium and zero law of thermodynamics -- 1.9 Summary of the chapter equations -- 2 -- Work, heat, internal energy, and enthalpy -- Introduction -- 2.1 The first law of thermodynamics: principles -- 2.1.1 Energy change: definition -- 2.1.2 Mathematic statement -- 2.2 First case: isothermal expansion of perfect gas -- 2.2.1 Into vacuum -- 2.2.2 Against constant pressure (irreversible). |
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2.12 Summary of the chapter equations -- 3 -- Entropy: the second and third laws of thermodynamics -- Introduction -- 3.1 The second law of thermodynamics -- 3.1.1 Definition -- 3.1.2 Stability -- 3.1.3 Thermodynamic stability -- 3.1.4 Kinetic stability -- 3.2 Entropy -- 3.2.1 Definition -- 3.2.2 Entropy and thermodynamic parameters -- 3.2.3 Principle of Clausius -- 3.3 Carnot cycle -- 3.3.1 Reversible cycle -- 3.3.2 The network: estimation -- 3.3.3 Efficiency: definition and estimation -- 3.3.4 Kelvin scale and absolute zero -- 3.3.5 Reversible versus irreversible cycle -- 3.4 Entropy basics -- 3.4.1 Entropy equation -- 3.4.2 Entropy and spontaneity -- 3.4.3 Statement of the second law -- 3.5 Calculating the entropy change -- 3.5.1 First case: a change of state at constant temperature -- 3.5.2 Second case: a perfect gas changing volume at constant temperature -- 3.5.3 Third case: a substance being heated or cooled over temperature range -- 3.5.4 Fourth case: an ideal gas undergoing an adiabatic irreversible expansion -- 3.5.5 Entropy change for a chemical reaction -- 3.5.6 Entropy and probability -- 3.5.7 The third law of thermodynamics and absolute entropy -- 3.5.8 Absolute entropy equation -- 3.5.9 Entropy of mixing -- 3.6 Entropy and internal energy relationships -- 3.6.1 Entropy versus internal energy and volume as independent variables, fundamental equation -- 3.6.2 Entropy and internal energy at constant volume -- 3.6.3 Entropy and volume at constant internal energy -- 3.6.4 Internal energy and volume at constant entropy -- 3.7 Entropy and enthalpy relationships -- 3.7.1 Entropy versus enthalpy and pressure as independent variables, fundamental equation -- 3.7.2 Entropy and enthalpy at constant pressure -- 3.7.3 Enthalpy and pressure at constant entropy -- 3.8 Entropy, temperature, pressure, and volume. |
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3.8.1 Entropy versus temperature and volume as independent variables, fundamental equation -- 3.8.2 Entropy and temperature at constant volume -- 3.8.3 Entropy and volume at constant temperature -- 3.8.4 Entropy versus temperature and volume as independent variables -- 3.8.5 Entropy versus temperature and pressure as independent variables -- 3.8.6 Relations involving entropy -- 3.8.7 Total and partial derivative expressions -- 3.8.8 Entropy and temperature at constant pressure -- 3.8.9 Entropy and volume at constant pressure -- 3.8.10 Entropy and temperature at constant volume -- 3.8.11 Entropy versus temperature and volume as independent variables: fundamental equation -- 3.8.12 Maxwell relations -- 3.9 Summary of the chapter equations -- 4 -- Free energy of pure substance in single phase -- Introduction -- 4.1 Free energy: principles -- 4.1.1 Definition -- 4.1.2 Defining equations -- 4.2 Gibbs energy and total entropy: equations and conditions -- 4.3 Gibbs energy and reversibility -- 4.4 The basic equations for free energy -- 4.4.1 Gibbs energy taking pressure and temperature as independent variables -- 4.4.2 Helmholtz energy taking volume and temperature as independent variables -- 4.5 Equilibrium conditions -- 4.5.1 Constant entropy and volume -- 4.5.2 Constant entropy and pressure -- 4.5.3 Constant pressure and temperature -- 4.6 Free energy and maximum expansion work -- 4.7 Isothermal free energy change -- 4.7.1 Ideal gases, liquid, and solid -- 4.7.2 Chemical reactions -- 4.7.3 Chemical activity: fundamental equation -- 4.8 Relations involving free energy: total and partial derivative expressions -- 4.8.1 Gibbs change taking pressure and temperature as independent variables -- 4.8.2 Helmholtz change taking volume and temperature as independent variables -- 4.8.3 Maxwell relations -- 4.8.4 Internal pressure -- 4.8.5 Internal energy. |
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4.8.6 Enthalpy -- 4.8.7 Entropy -- 4.9 Free energy, temperature, pressure, and volume -- 4.9.1 Free energy and pressure at constant temperature -- 4.9.2 Free energy and volume at constant temperature -- 4.9.3 Free energy taking pressure and volume as independent variable -- 4.9.4 Free energy and temperature at constant pressure -- 4.9.5 Free energy and volume at constant pressure -- 4.9.6 Free energy taking volume and temperature as independent variable -- 4.9.7 Free energy and pressure at constant volume -- 4.9.8 Free energy and temperature at constant volume -- 4.9.9 Gibbs energy change taking pressure and temperature as independent variable -- 4.9.10 Isothermal Gibbs energy change with pressure -- 4.9.11 Isothermal Gibbs energy change with volume changes -- 4.9.12 Helmholtz energy with temperature at constant volume -- 4.9.13 Helmholtz energy versus the change of volume at constant temperature -- 4.9.14 Enthalpy-entropy parallel behavior at constant temperature and pressure -- 4.10 Chemical potential -- 4.10.1 Definition -- 4.10.2 Chemical potential change at constant temperature -- 4.10.3 Chemical potential change at constant pressure -- 4.10.4 Chemical potential and fugacity -- 4.10.5 Real and standard state -- 4.10.6 Thermodynamic quantities and fugacity coefficient -- 4.10.7 Thermodynamic quantities and virial coefficient -- 4.11 Summary of the chapter equations -- 5 -- Thermodynamics of homogeneous and heterogeneous systems -- Introduction -- 5.1 Variables for open homogeneous system: principles -- 5.2 Chemical potential and thermodynamics functions: basic equation -- 5.3 Meaning of the chemical potential -- 5.4 Partial molar quantities: definition -- 5.5 Equilibrium conditions in open systems: applications -- 5.6 Chemical potential and mole fraction: fundamental equation. |
| Subject |
Thermodynamics.
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Chemical equilibrium.
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Chemical reactions.
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Statistical thermodynamics.
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Thermodynamique.
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Équilibre chimique.
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Thermodynamique statistique.
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thermodynamics.
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Chemical equilibrium
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Chemical reactions
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Statistical thermodynamics
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Thermodynamics
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| Added Author |
Addison, Anthony W.
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| Other Form: |
Print version: Stephanos, Joseph J. Chemical Thermodynamics and Statistical Aspects San Diego : Elsevier,c2023 9780443152955 |
| ISBN |
9780443152962 electronic book |
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0443152969 electronic book |
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9780443152955 |
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0443152950 |
| Standard No. |
AU@ 000074837754 |
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