| Edition |
First edition. |
| Description |
1 online resource (316 pages) : illustrations, tables |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Series |
Advances in Organometallic Chemistry, 0065-3055 ; Volume 62 |
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Advances in organometallic chemistry ; Volume 62.
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| Bibliography |
Includes bibliographical references at the end of each chapters and index. |
| Note |
Online resource; title from PDF title page (ebrary, viewed October 8, 2014). |
| Summary |
This book contains authoritative reviews regarding the field of Organometallic Chemistry, written by highly qualified experts within the area, and reviewed by other experts before publication. Because of this high standard, AOC is one of the most cited journals in both Organic and Inorganic Chemistry fields. |
| Contents |
Front Cover; Advances in Organometallic Chemistry; Copyright; Contents; Contributors; Chapter One: Palladium-Mediated Organofluorine Chemistry; 1. Introduction; 2. CC Coupling Reactions of Fluorinated Reagents; 2.1. Overview of catalytic CC coupling reactions of fluorinated derivatives; 2.1.1. CC coupling of fluorinated alkyl derivatives; 2.1.1.1. Radical reactions; 2.1.1.2. Perfluoroalkyl groups in the Stille reaction; 2.1.1.3. Introduction of fluorinated groups using the Negishi reaction; 2.1.1.4. Introduction of fluorinated groups using the Suzuki reaction. |
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2.1.1.5. Use of fluoroalkyl silanes as fluoroalkylating reagents2.1.1.6. Other fluoroalkylating reagents: Fluoroalkyl copper; 2.1.1.7. Allylic alkylation reactions; 2.1.1.8. Catalysis through palladium mediated CH activation; 2.1.1.9. Perfluoroalkylation of unsaturated molecules; 2.1.2. CC coupling of fluorinated aryl derivatives; 2.1.2.1. Heck reactions; 2.1.2.2. Suzuki-Miyaura reactions; 2.1.2.3. Stille reactions; 2.1.2.4. Sonogashira reactions; 2.1.3. CC coupling of fluorinated arenes; 2.1.4. CC coupling of fluorinated alkenyls; 2.2. The PdRF bond; 2.2.1. PdAlkylF bonds; 2.2.2. PdArF bonds. |
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2.3. Elementary steps in organofluorine CC coupling palladium-catalyzed processes2.3.1. Oxidative addition and related processes; 2.3.1.1. Oxidative addition to Pd(0) compounds; 2.3.1.2. Oxidation of Pd(II) compounds leading to organofluorine Pd(IV) derivatives; 2.3.2. Transmetalation; 2.3.2.1. The transmetalation step in the Stille reaction; 2.3.2.2. Transmetalation equilibria between organogold and organopalladium complexes; 2.3.2.3. The transmetalation step in the Negishi reaction; 2.3.3. Reductive elimination; 2.3.3.1. Reductive elimination from Pd(II) complexes. |
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2.3.3.2. Reductive elimination from Pd(IV) complexes2.3.4. 2,1-Insertion; 2.3.5. 1,1-Insertion (migratory insertion); 3. CF Activation and Fluorination; 3.1. Overview of catalytic CC and CX coupling reactions where a CF bond is cleaved; 3.1.1. CC coupling reactions of fluorinated aryls; 3.1.2. CC Coupling reactions of fluorinated alkenes; 3.1.3. Allylic substitutions of a fluorine atom; 3.1.4. Hydrodefluorination reactions; 3.2. Overview of catalytic CF forming reactions; 3.2.1. Pd-catalyzed fluorination with electrophilic fluorine sources. |
| Subject |
Organometallic chemistry.
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Chimie organométallique.
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Organometallic chemistry
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| Added Author |
Perez, Pedro J., 1965- editor.
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Stone, F. Gordon A., editor.
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West, Robert, editor.
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Achard, Mathieu, contributor.
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| Other Form: |
Print version: Advances in organometallic chemistry. Volume sixty two. First edition. London, England : Academic Press, ©2014 vii, 307 pages Advances in organometallic chemistry ; Volume 62 0065-3055 9780128009765 |
| ISBN |
9780128010846 (electronic bk.) |
|
0128010843 (electronic bk.) |
|
9780128009765 |
| Standard No. |
CHBIS 010549950 |
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CHVBK 341933872 |
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DEBSZ 431794227 |
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GBVCP 825920604 |
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AU@ 000056024372 |
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AU@ 000068486757 |
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