| Description |
1 online resource (x, 447 pages). |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Series |
Advances in inorganic chemistry ; v. 55 |
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Advances in inorganic chemistry ; v. 55.
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| Note |
Print version record. |
| Bibliography |
Includes bibliographical references and index. |
| Summary |
Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. . Comprehensive reviews written by leading experts in the field . An indispensable reference to advanced researchers . Includes 7 contributions covering important advances in inorganic chemistry. |
| Contents |
Front Cover; Advances in Inorganic Chemistry; Copyright Page; Contents; Preface; Chapter 1. Dioxygen Activation by Transition Metal Complexes. Atom Transfer and Free Radical Chemistry in Aqueous Media; I. Introduction; II. Preparation and Characterization; III. Reactivity; IV. Conclusions and Future Directions; V. Abbreviations; References; Chapter 2. Redox Reactivity of Coordinated Ligands in Pentacyano(L)Ferrate Complexes; I. Introduction; II. General Properties of the Nitroprusside ion, [Fe(CN)5NO]2- (NP), and Related Nitrosyl Complexes |
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III. The Coordination Chemistry of NO. Formation and Dissociation ReactionsIV. The Redox Reactivity of Bound NO; V. The Electrophilic Reactions of Bound NO; VI. The Autooxidation of Hydrazine; VII. The Oxidation of Amines and Alcohols; VIII. The Disproportionation of Hydroxylamine; IX. Miscellaneous Reactions; X. Conclusions; References; Chapter 3. Carbonato Complexes: Models for Carbonic Anhydrase; I. Introduction; II. Carbonic Acid, Bicarbonate, and Carbonate; III. The Chemistry of Metal Carbonates; IV. Kinetics and Mechanism of Formation and Aquation/Decarboxylation Reactions |
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IV. FerrocenesV. Osmium and Ruthenium Compounds; VI. Chiral Complexes; VII. Cyclometalated Ruthenium(II) and Osmium(II)Mediators; VIII. Concluding Remarks; References; Chapter 5. Properties of Transition Metal Complexes with Metal-Carbon Bonds in Aqueous Solutions as Studied by Pulse Radiolysis; I. Introduction; II. Radiolysis of Aqueous Solutions; III. Reaction of Aliphatic Carbon-Centered Radicals with TransitionMetal Complexes in Aqueous Solutions; IV. Formation of Transition Metal Complexes with Metal-Carbon s-Bonds; V. Properties of Complexes with Metal-Carbon s-Bonds |
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VI. Mechanisms of Decomposition of the Transient Complexes LmMn+1-RVII. Alkene Complexes; VIII. Complexes with Metal-Carbon s-Bonds Formed in Redox Processes Between Transition Metal Complexes and Organic Substrates; IX. Elucidation of the Mechanisms of Catalytic Processes; References; Chapter 6. Transition Metal Complexes with Bis(Hydrazone) Ligands of 2,6-Diacetylpyridine. Hepta-Coordination of 3d Metals; I. Introduction; II. Aspects Studied; III. Concluding Discussion; References; Chapter 7. Potential Applications for the Use of Lanthanide Complexes as Luminescent Biolabels; I. Scope |
| Language |
English. |
| Subject |
Chemistry, Inorganic.
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Chemistry.
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Chemistry, Inorganic |
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Chemistry |
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Chimie inorganique.
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Chimie.
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inorganic chemistry.
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chemistry.
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Chemistry
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Chemistry, Inorganic
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| Added Author |
Eldik, Rudi van.
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| Other Form: |
0-12-023655-9 |
| ISBN |
0120236559 (electronic bk.) |
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9780120236558 (electronic bk.) |
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1281010529 |
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9781281010520 |
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9786611010522 |
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6611010521 |
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0080493661 |
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9780080493664 |
| Standard No. |
CHBIS 010355368 |
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CHVBK 329770969 |
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DEBSZ 405333420 |
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