| Description |
1 online resource (12 pages) : color illustrations. |
|
text txt rdacontent |
|
computer c rdamedia |
|
online resource cr rdacarrier |
| Series |
NREL/PR ; 5500-78503 |
|
NREL/PR ; 5500-78503.
|
| Note |
Some text obscured by image on page 3. |
|
Description based on online resource, PDF version; title from title page (National Renewable Energy Laboratory, viewed July 6, 2022). |
| Summary |
The use of phase change materials (PCMs) in thermal energy storage applications has received considerable attention in recent decades. Organic PCMs are popular due to their high latent heat of fusion, noncorrosive properties, and relative stability over many charge and discharge cycles. A primary limitation of these materials is their low thermal conductivity. This has led researchers to develop various methods to increase thermal conductivity by seeding PCM with or impregnating them into more conductive materials. One method is to impregnate PCMs into compressed expanded natural graphite (CENG) matrices, which can improve thermal conductivity by a factor of 100. CENG matrices have received particular interest due to their low cost, high porosity, small (nano/micro) pore size, high pore density, high thermal conductivity, and ability to be compressed into many geometries. PCM/CENG matrix composites have been extensively studied; however, the effect that CENG processing has on PCM saturation and the overall matrix thermal conductivity has not been well investigated. This processing includes four major steps including graphite intercalation, thermal shock, compression, and PCM saturation. Intercalation involves soaking graphite flakes in sulfuric and/or nitric acid to intercalate the acids between the graphene layers. The graphite flakes are then subjected to a high-temperature thermal shock, during which the intercalated acid is gasified rapidly, pushing the graphene layers apart, resulting in accordion-shaped graphite "worms". The "worms" are then compacted to a desired bulk density and then soaked with molten PCM until fully saturated. The properties of the produced CENG matrix, and its ability to allow PCM permeation, are sensitive to the processing parameters, namely, the thermal shock temperature and exposure time, as well as the matrix apparent density or porosity. Here, we study the effect of the thermal shock conditions necessary to expand intercalated graphite flakes on PCM saturation and the expanded graphite's thermal conductivity and morphology. We found that the thermal shock temperature exhibits the greatest influence. At greater shock temperatures, SEM images showed that expanded graphite worms exhibited greater density of pores, thus increasing total surface area within the matrices. Increasing thermal shock temperature yielded greater overall PCM saturation, as well as an increased rate of saturation. Improvements in PCM saturation rate and overall saturation are obtained as the shock temperature is increased. Longer exposure to thermal shock also improves initial saturation rates and is beneficial if a shortened impregnation time is needed. Thermal shock conditions did not impact thermal conductivity; however, conductivity was largely affected by matrix porosity. A local maximum in axial thermal conductivity was observed at around 83% porosity, which is similar to that observed in previous studies. |
| Subject |
Graphite composites -- Research -- United States.
|
|
Graphite composites -- Thermal conductivity -- United States.
|
|
Phase rule and equilibrium -- Experiments.
|
|
Composites de graphite -- Recherche -- États-Unis.
|
|
Composites de graphite -- Conductivité thermique -- États-Unis.
|
|
Loi des phases et équilibre -- Expériences.
|
|
Phase rule and equilibrium -- Experiments
|
|
United States https://id.oclc.org/worldcat/entity/E39PBJtxgQXMWqmjMjjwXRHgrq
|
| Indexed Term |
compressed expanded natural graphite |
|
phase change composite |
|
phase change materials |
|
porous material composite |
|
thermal conductivity enhancement |
|
thermal energy storage |
| Added Author |
National Renewable Energy Laboratory (U.S.), issuing body.
|
| Added Title |
Compressed expanded natural graphite (CENG) processing for phase change material composites |
| Running Title |
IMECE Paper #2020-57432 |
| Standard No. |
0000-0002-6764-6848 |
|
0000-0002-9560-9964 |
|
0000-0002-7661-2658 |
| Gpo Item No. |
0430-P-09 (online) |
| Sudoc No. |
E 9.22:NREL/PR-5500-78503 |
|
