| Edition |
First edition. |
| Description |
1 online resource (286 pages) : illustrations |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Note |
Description based on print version record. |
| Contents |
Front Cover -- Advances in Organometallic Chemistry -- Copyright -- Contents -- Contributors -- Preface -- Chapter One: Water oxidation at base metal molecular catalysts -- 1. Introduction -- 1.1. Water oxidation in nature. The oxygen evolving complex -- 1.2. Synthetic models for the natural water oxidation reaction -- 1.3. Oxidants in water oxidation reactions -- 1.4. General mechanisms for water oxidation -- 1.5. Typology of catalysts -- 2. Model well-defined water oxidation catalysts -- 2.1. Manganese water oxidation catalysts -- 2.1.1. Catalytic water oxidation with manganese coordination complexes -- 2.1.2. Water oxidation with polyphosphate and polycarboxylate manganese complexes -- 2.2. Water oxidation with molecular iron catalysts -- 2.2.1. Iron catalysts with tetraanionic tetraamido macrocyclic ligands -- 2.2.2. Iron catalysts with aminopyridine ligands -- 2.2.3. Water oxidation with an anionic polyamine ligand -- 2.2.4. Water oxidation at oxo-bridged diiron complexes -- 2.2.5. Water oxidation at a multiiron complex -- 2.3. Cobalt water oxidation catalysts -- 2.3.1. Cobalt Polyoxometalates -- 2.3.2. Cobalt complexes with planar macrocyclic ligands: Porphyrin, phthalocyanin, corrole and TAMLs ligands -- 2.3.3. Coordination compounds based on poly-amine/pyridyl ligands -- 2.3.4. Salen type cobalt complexes -- 2.3.5. Cobalt oxide clusters -- 2.4. Nickel-based water oxidation catalysts -- 2.4.1. Coordination compounds containing N-based ligands for electrocatalytic water oxidation -- 2.5. Copper-based water oxidation catalysts -- 3. Conclusion and outlook -- Acknowledgments -- References -- Further reading -- Chapter Two: Surface coordination chemistry on graphene and two-dimensional carbon materials for well-defined single atom ... -- 1. Introduction -- 2. The surface chemistry of graphene and two-dimensional carbon materials. |
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2.1. Graphene -- 2.2. Graphene oxide -- 2.3. Graphitic carbon nitride -- 2.4. Graphyne and graphdiyne -- 3. Well-defined single atom supported catalysts characterization -- 4. Surface coordination chemistry involving coordination complexes-site-isolated heterogeneous catalysts -- 4.1. Noncovalent interactions -- 4.2. Covalent interactions -- 4.2.1. Covalent bond between ligand or complex and carbon of the surface -- 4.2.2. Covalent bond between ligand or complex and -OH surface group -- 4.2.3. Covalent bond between ligand or complex and -COOH surface groups -- 4.2.4. Covalent bond between ligand or complex involving epoxide surface groups -- 5. Surface coordination chemistry involving single metallic atoms -- 5.1. Low metal loading SACs -- 5.1.1. Atomic layer deposition -- 5.1.2. Wet chemistry methods -- 5.1.3. Thermal post-treatments -- 5.1.4. Electrochemical methods -- 5.2. High metal loading SACs -- 6. Catalytic applications -- 6.1. Reduction reactions -- 6.2. Oxidation reactions -- 6.3. Coupling reactions -- 6.4. Polymerization and other reactions -- 6.5. Electrocatalysis -- 6.5.1. Oxygen reduction reaction -- 6.5.2. Hydrogen and oxygen evolution reactions -- 6.5.3. Carbon monoxide and carbon dioxide electroreduction -- 6.5.4. Electrocatalytic oxidation reactions -- 6.6. Photocatalysis -- 6.6.1. Hydrogen evolution reaction -- 6.6.2. Carbon dioxide photoreduction -- 6.6.3. Photodegradation and oxidation reactions -- 6.6.4. Other visible light assisted reactions -- 7. Conclusion -- References -- Chapter Three: Catalytic nonreductive valorization of carbon dioxide into fine chemicals -- 1. Introduction -- 2. Coupling reactions between CO2 and small cyclic ethers -- 2.1. Metal catalyzed couplings of terminal epoxides -- 2.2. Metal catalyzed couplings of internal epoxides -- 2.3. Transformations based on highly substituted substrates. |
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2.4. Cycloaddition reactions using oxetanes -- 3. Catalytic transformations of cyclic carbonates -- 4. Organometallic catalysis using decarboxylative chemistry -- 4.1. Cyclic carbonates as allylic surrogates -- 4.2. Alkynyl-substituted cyclic carbonates -- 4.3. Cyclic carbonates in C-H activation -- 4.4. Miscellaneous decarboxylative transformations -- 5. Conclusion and outlook -- Acknowledgments -- References -- Chapter Four: Gold and platinum alkynyl complexes for biomedical applications -- 1. Introduction -- 2. Gold alkynyl derivatives -- 2.1. Alkynyl complexes with triphenylphosphane as ancillary ligand -- 2.2. Alkynyl complexes with different phosphanes as ancillary ligands -- 2.3. Polynuclear gold alkynyl derivatives -- 2.4. Alkynyl gold derivatives with fluorophore ligands -- 2.5. Alkynyl carbene gold derivatives -- 3. Platinum alkynyl derivatives -- 3.1. Glycosylated alkynyl platinum complexes with terpyridine ligands -- 3.2. Alkynyl platinum complexes with COD ligands -- 3.3. Alkynyl platinum complexes with planar polyaromatic ligands -- 3.4. Dinuclear alkynyl platinum complexes -- 3.5. Alkynyl platinum complexes as photosensitizers (PSs) -- 3.6. Dual alkynyl platinum-based photosensitizers and photoimaging agents -- 4. Conclusions -- Acknowledgments -- References -- Chapter Five: Transition metal-catalyzed hydrogenation of carbon dioxide in ionic liquids -- 1. Introduction -- 1.1. Carbon dioxide hydrogenation to formic acid/formate -- 1.2. CO2 Fischer-Tropsch synthesis -- 2. Catalytic hydrogenation of CO2 to formic acid/formate in ILs -- 3. Catalytic hydrogenation of CO2 to hydrocarbons (HCs) in ILs -- 4. Hydroformylation and amino-carbonylation with CO2 in ILs -- 5. Conclusions -- Acknowledgments -- References -- Back Cover. |
| Subject |
Organometallic chemistry.
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Organometallic compounds.
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Chimie organométallique.
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Composés organométalliques.
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organometallic compound.
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| Added Author |
Perez, Pedro J., 1965- editor.
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| ISBN |
0128171162 |
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9780128171165 |
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0128171154 |
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9780128171158 |
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