| Description |
1 online resource |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Note |
Online resource; title from PDF title page (EBSCO, viewed November 29, 2018). |
| Summary |
Kinetic Control in Synthesis and Self-Assembly provides a unique overview of the fundamental principles, novel methods and practical applications for researchers across organic synthesis, supramolecular chemistry and materials sciences. The book examines naturally occurring molecular systems in which kinetic processes are more ubiquitous than thermodynamic processes, also exploring the control of reactions and molecular self-assemblies, through kinetic processes, in artificial systems. These methods currently play a crucial role for tuning materials functions. From organic synthesis, to supramolecular assemblies, and from restricted spaces, to material synthesis for hierarchical structures, the book offers valuable coverage for researchers across disciplines. Interesting topics include how to regulate kinetic pathways more precisely, essential molecular design for kinetic traps, and how molecular environments surrounding molecules (i.e., solvent, temperature, and pressure effects) influence kinetic control in reactions and self-assemblies. |
| Contents |
3.2 Kinetic Products and Thermodynamic Products in Ring Closure Reaction of S-DR33.3 Kinetic Stabilization by Bulky Aryl Group; 4. KINETIC STABILIZATION BY ``STRETCH EFFECT''; 4.1 Type 1: Spirobonding; 4.2 Type 2: Macrocyclic System; 5. SUMMARY; REFERENCES; 2 -- Dynamic Kinetic Resolution for Asymmetric Synthesis: Synergy of Hydrolase and Metal Catalysts; 1. INTRODUCTION; 2. GENERAL ASPECTS OF HYDROLASE-CATALYZED KINETIC RESOLUTION AND DYNAMIC KINETIC RESOLUTIONS; 3. HYDROLASE/METAL COMBO-CATALYZED DYNAMIC KINETIC RESOLUTION; 4. SYNTHETIC APPLICATIONS OF DYNAMIC KINETIC RESOLUTION; 5. SUMMARY |
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3.2 Divergent Synthesis of Polyacene Derivatives4. CONCLUSION; REFERENCES; 4 -- Control of Inversion Kinetics of Bowl-Shaped Aromatic Compounds; 1. INTRODUCTION; 2. PRISTINE BUCKYBOWLS; 3. SUBSTITUTED BUCKYBOWLS; 4. HETEROBUCKYBOWLS; 5. SUMMARY; REFERENCES; 5 -- Asymmetric Hydrogenation of Aromatic Carbocycles; 1. INTRODUCTION; 2. ASYMMETRIC HYDROGENATION OF AROMATIC CARBOCYCLES WITH CHIRAL AUXILIARY; 3. CATALYTIC ASYMMETRIC HYDROGENATION OF AROMATIC CARBOCYCLES; 4. SUMMARY; REFERENCES; 6 -- Kinetic Control in Natural Product Synthesis; 1. INTRODUCTION; 2. PALAU'AMINE |
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3. SYNTHESIS OF CYCLIZATION PRECURSOR 44. SINGLE-STEP CONSTRUCTION OF ABDE TETRACYCLIC RING CORE USING KINETIC CONTROL CONDITION; 5. TOTAL SYNTHESIS OF PALAU'AMINE; 6. CONCLUSION; REFERENCES; 7 -- Influence of Glycosylation Pattern on Protein Biodistribution and Kinetics In Vivo Within Mice; 1. INTRODUCTION; 2. SYNTHETIC METHODS OF N-GLYCOSYLATED PROTEINS; 2.1 Lysine Residue Conjugation; 2.2 Cysteine Residue Conjugation; 2.3 Bioorthogonal Reaction-Based Conjugation; 2.4 Enzymatic Glycosylation; 3. IMAGING METHODS FOR N-GLYCOSYLATED PROTEIN BIODISTRIBUTION |
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Front Cover; KINETIC CONTROL IN SYNTHESIS AND SELF-ASSEMBLY; KINETIC CONTROL IN SYNTHESIS AND SELF-ASSEMBLY; Copyright; CONTENTS; CONTRIBUTORS; PREFACE; SUMMARY OF CONTENTS; 1 -- Kinetic Stabilization of Localized Singlet Diradicaloids With? Single Bonding Character; 1. INTRODUCTION; 2.? SINGLE-BONDED SPECIES; 2.1? Single Bond; 2.2 Construction of? Single Bonds; 2.3 Generation and Reactivity of Localized Singlet Diradicaloids With? Single-Bonding Character; 3. KINETIC STABILIZATION USING BULKY SUBSTITUENTS; 3.1 Alkoxy Group Effect |
| Subject |
Organic compounds -- Synthesis.
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Self-assembly (Chemistry)
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Supramolecular chemistry.
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Chemical kinetics.
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Composés organiques -- Synthèse.
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Autoassemblage.
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Chimie supramoléculaire.
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Cinétique chimique.
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SCIENCE -- Chemistry -- Organic.
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Chemical kinetics
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Organic compounds -- Synthesis
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Self-assembly (Chemistry)
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Supramolecular chemistry
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| Added Author |
Numata, Munenori, editor.
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Yagai, Shiki.
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Hamura, Toshiyuki.
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| Other Form: |
Print version: Kinetic Control in Synthesis and Self-Assembly. London : Elsevier Ltd. : Academic Press, 2018 0128121262 9780128121269 (OCoLC)1027119194 |
| ISBN |
9780128121276 (electronic bk.) |
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0128121270 (electronic bk.) |
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9780128121269 |
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0128121262 |
| Standard No. |
UKMGB 019154667 |
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AU@ 000064521798 |
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