| Edition |
First edition. |
| Description |
1 online resource (324 pages) |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Contents |
Front Cover -- Series page -- Title page -- Copyright -- Contents -- Contributors -- Preface -- Chapter One: Nitrides stepping up: Terminal nitrido complexes in nitrogen fixation and nitrogen atom transfer reactionsNitrides stepping up -- 1 Introduction -- 1.1 Terminal transition metal nitrido ligands: Chemical bonding -- 1.2 Terminal transition metal nitrido ligands: Reactivity trends -- 2 Reductive N2 splitting into molecular nitrides -- 2.1 Group 6 (molybdenum, tungsten) -- 2.2 Group 7 (rhenium) -- 3 Nitride transfer -- 3.1 Group 6 (tungsten) -- 3.2 Group 7 (rhenium) -- 3.3 Group 8 (ruthenium, osmium) -- 3.4 Group 9 (rhodium, iridium) -- 3.5 Group 10 (palladium, platinum) -- 4 Conclusions -- References -- Chapter Two: Aminopyridinato ligand complexes-Precursors for nanocomposite catalysts, quintuple bonding and on-purpose olefin synthesisAminopyridinato ligand complexes -- 1 The aminopyridinato (Ap) ligand for the cyclopentadienyl (Cp) ligand concept -- 2 Precursors for nanocomposite catalysts -- 3 Quintuple bonding -- 4 On-purpose olefin syntheses -- References -- Chapter Three: Advancing metal-organic frameworks' materials chemistry -- 1 Introduction -- 2 Flexible MOFs -- 3 Surface-mounted MOFs -- 4 Non-linear optical effects of MOFs -- 5 Metal loading to MOFs -- 6 Thermal catalysis with MOFs -- 7 Photocatalysis with MOFs -- 8 Electrocatalysis with SURMOFs -- 9 MOF-derived materials for energy -- 10 MOF-based hybrids for environment and health -- Acknowledgments -- References -- Chapter Four: Recent advances in low-valent silicon chemistry -- 1 Introduction -- 2 Bis(silylene)s for stabilizing low-valent main-group elements -- 2.1 Low-valent group 14 complexes -- 2.1.1 Pyridine-based bis(NHSi) supported Ge0 complexes -- 2.1.2 Ortho-carborane-based bis(NHSi) supported silicon(0) and germanium(0) complexes. |
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2.1.3 Xanthene-based bis(NHSi) supported silicon(0), germanium(0), tin(0), and lead(0) complexes -- 2.2 Low-valent group 15 complexes -- 2.2.1 Ortho-carborane-based bis(NHSi) supported low-valent N and P complexes -- 2.2.2 Aniline-based bis(NHSi)-supported low-valent P complexes -- 2.2.3 Xanthene-based bis(NHSi)-ligated low-valent P complexes -- 3 Bis(silylene)s for cooperative small molecule activation -- 3.1 Oxidation reactions with O2, N2O and CO2 -- 3.2 Activation of CO2 and CS2 with ligand participation -- 3.3 CO activation and further functionalization with NH3 -- 3.4 Formation of diradicals for CO activation -- 4 Mono- and bis(silylene) transition-metal complexes in homogeneous catalysis -- 4.1 Group 7-Mn -- 4.1.1 MnII complexes for the transfer semi-hydrogenation of alkynes -- 4.1.2 Mn0 complexes for the selective hydroboration of N-heteroarenes -- 4.2 Group 8-Fe -- 4.2.1 Fe0 Complexes for the hydrosilylation or hydrogenation of ketones -- 4.2.2 FeII complexes for the reduction of N2O and nitro compounds -- 4.3 Group 9-Co, Rh, Ir -- 4.3.1 CoI complexes for the [2 + 2 + 2] cycloaddition of phenylacetylene -- 4.3.2 CoII complexes for the regioselective C-H borylation of arenes and heterocycles -- 4.3.3 IrIII and RhIII complexes for the C-H borylation of arenes -- 4.3.4 IrI and RhI complexes for the reduction of amides -- 4.3.5 RhI complexes for the hydroformylation of styrene -- 4.3.6 RhIII complexes for the alkylation of aryl pyridines -- 4.4 Group 10-Ni, Pd -- 4.4.1 NiII complexes for Sonagashira cross-coupling -- 4.4.2 NiII and Ni0 complexes for the Buchwald-Hartwig amination of arenes -- 4.4.3 Ni0 and NiII complexes for Negishi and Kumada cross-coupling -- 4.4.4 Ni0 complexes for the hydrogenation of olefins -- 5 Conclusion and outlook -- Acknowledgment -- References. |
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Chapter Five: CO2 capture, reduction, and utilization by silicon and aluminum compounds and their mechanistic waysCO2 capture, reduction, and utilization -- 1 Introduction -- 2 Silicon meets carbon dioxide -- 2.1 Silylenes -- 2.2 Bis-silylenes -- 2.2.1 CO2 reactivity of Si?E silicon double bonds -- 2.2.2 Silyliumylidenes -- 2.3 Silylone -- 3 Aluminum meets carbon dioxide -- 3.1 Alanes -- 3.2 Aluminum hydrides -- 3.3 Aluminum Lewis pairs -- 3.4 Dialumenes -- 3.5 Anionic alumanyls -- 3.6 Heterobimetallic aluminum compounds -- 4 Conclusion -- Acknowledgments -- References -- Chapter Six: Late transition metal-ligand multiple bonds: Covalency and reactivity -- 1 Contents -- 1.1 Introduction -- 2 Electronic structure of complexes with metal-ligand multiple bonds -- 3 Covalency and reactivity-General -- 3.1 Complexes in high oxidation states -- 3.2 Complexes in higher spin states -- 3.3 Group 10 and 11 complexes -- 3.4 Coordination of redox-innocent cations -- 4 Concluding remarks -- References -- Chapter Seven: Bismuth-based Lewis acidityBismuth-based Lewis acidity -- 1 Introduction -- 2 Orbital interactions of bismuth-based Lewis acids -- 3 Means of assessing Lewis acidity -- 4 Hard vs soft Lewis acids -- 5 The role of charge in Lewis acidity -- 6 Tuning Lewis acidity by geometric constraints and steric bulk -- 7 Solvent effects -- 8 Number and accessibility of Lewis acidic sites -- 9 Metal-only Lewis pairs -- 10 Impact of Lewis acidity on reactivity -- 11 Conclusions -- References -- Chapter Eight: Structural constraint effects on p-block elements: Recent advances -- 1 Introduction -- 2 Structural deformations classified according to symmetry species, Walsh diagrams, and correlations with molecular inversion -- 2.1 Deformation of C3v structures -- 2.2 Deformation of D3h structures -- 2.3 Deformation of Td structures. |
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3 Experimental advances in the C3v to C2v deformation (trigonal pyramidal to T-shape) -- 4 Experimental advances in the D3h to C3v deformation (trigonal planar to pyramidal) -- 5 Experimental advances in the Td to D4h deformation (tetrahedral to square planar) -- 6 Experimental advances in the C2v to C4v deformation -- References -- Index -- Backcover. |
| Note |
Description based on print version record. |
| Subject |
Chemistry -- Research -- Germany.
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Chemistry, Inorganic.
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Chimie -- Recherche -- Allemagne.
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Chimie inorganique.
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inorganic chemistry.
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Chemistry, Inorganic
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Chemistry -- Research
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Germany
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| Added Author |
Meyer, Karsten, author.
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| ISBN |
0443159459 |
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9780443159459 |
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0443159440 |
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9780443159442 |
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