| Edition |
Second edition. |
| Description |
1 online resource (232 pages) : illustrations |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Series |
Horwood Series in Chemical Science |
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Horwood Publishing series in chemical science.
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| Bibliography |
Includes bibliographical references and index. |
| Note |
Online resource; title from PDF title page (ebrary, viewed February 14, 2014). |
| Summary |
This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. Inorganic solution chemistry is treated thoroughlyEmphasis is placed upon NMR, UV-VIS, IR Raman spectroscopy, X-ray diffraction, and such topics as acid-base behaviour, stability constants and kinetics. |
| Contents |
Front Cover; Ions in Solution: Basic Principles of Chemical Interactions; Copyright Page; Table of Contents; Author's preface; List ofsymbols and abbreviations; Chapter 1. Introduction; 1.1 Dissolution of salts; 1.2 Metal ions around the Periodic Table; 1.3 New aqua-metal ions; 1.4 Anions and complexes in solution; 1.5 Model for ions in solution; Chapter 2. Solvation numbers; 2.1 NMR spectroscopy; 2.2 Ion movement methods; 2.3 Review of solvation numbers; Chapter 3. Ion-solvent distances; 3.1 X-ray diffraction by solutions; 3.2 Radial distribution functions. |
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3.3 Results of diffraction and scattering studiesChapter 4. Ion-solvent interactions; 4.1 Ultraviolet-visible spectroscopy; 4.2 Infrared and Raman spectroscopy; 4.3 Thermochemistry of ion solvation; Chapter 5. Acid-base behaviour; hydrolysis and polymerisation; 5.1 pK values for aqua-metal ions; 5.2 Polymerisation; 5.3 Anions and ligands; 5.4 Complexes; Chapter 6. Stability constants; 6.1 Definitions; 6.2 Trends; 6.3 Chelates; 6.4 Selectivity; macrocyclic and encapsulating ligands; 6.5 Relevance; Chapter 7. Redox potentials; 7.1 Introduction and thermodynamics; 7.2 Aqua-metal ions. |
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7.3 Complexes7.4 Redox potentials and stability constants; Chapter 8. Kinetics and thermodynamics; Chapter 9. Kinetics and mechanisms: solvent exchange; 9.1 Introduction; 9.2 Mechanisms; 9.3 Reactivities; Chapter 10. Kinetics and mechanisms: complex formation; 10.1 Background; 10.2 The Eigen-Wilkins mechanism; 10.3 Chelate formation; 10.4 Polydentate and macrocyclic ligands; 10.5 Crown ethers and cryptands; Chapter 11. Kinetics and mechanisms: substitution at complex ions; 11.1 General; 11.2 Cobalt(III) complexes; 11.3 Platinum(II) complexes; 11.4 Pentacyanoferrates(II); 11.5 Other complexes. |
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Chapter 12. Kinetics and mechanisms: redox reactions12.1 Introduction; 12.2 The inner-sphere mechanism; 12.3 The outer-sphere mechanism; 12.4 Intermediates, pre-equilibria, and other complications; 12.5 Metal ion oxidation of simple species; 12.6 Oxoanion oxidants; 12.7 lntramolecular electron transfer; Chapter 13. Past, present and future; Glossary; Further reading; Exercises, problems and projects; Index. |
| Subject |
Ionic solutions.
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Solution (Chemistry)
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Ions.
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Solutions ioniques.
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Solutions (Chimie)
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Ions.
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solution.
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MUSIC -- Instruction & Study -- Theory.
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Ionic solutions
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Ions
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Solution (Chemistry)
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| Other Form: |
Print version: Burgess, John. Ions in solution : basic principles of chemical interactions. Cambridge, England ; Philadelphia, Pennsylvania ; New Delhi, India : Woodhead Publishing, 2011, ©1999. Second edition. 222 pages Horwood Publishing series in chemical science. 9781898563501 |
| ISBN |
9781782420569 (electronic bk.) |
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1782420568 (electronic bk.) |
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9781898563501 |
| Standard No. |
AU@ 000055963367 |
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DEBBG BV042313726 |
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DEBSZ 414274199 |
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GBVCP 79700971X |
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UKMGB 017568031 |
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