Kids Library Home

Welcome to the Kids' Library!

Search for books, movies, music, magazines, and more.

     
Available items only
Electronic Book
Author Stephanos, Joseph J.

Title Chemical Thermodynamics and Statistical Aspects : Questions to Ask in Fundamentals and Principles.

Publication Info. San Diego : Elsevier, 2023.

Copies

Location Call No. OPAC Message Status
 Axe Elsevier ScienceDirect Ebook  Electronic Book    ---  Available
Description 1 online resource (1458 p.)
text txt rdacontent
computer c rdamedia
online resource cr rdacarrier
Contents Front Cover -- Chemical Thermodynamics and Statistical Aspects -- Chemical Thermodynamics and Statistical Aspects -- Copyright -- Contents -- Preface -- I -- Chemical thermodynamics -- 1 -- Thermodynamics: principles and fundamentals -- Introduction -- 1.1 Principles and definitions -- 1.1.1 Thermodynamic systems and processes -- 1.1.2 Thermodynamic variables -- 1.1.3 Essential thermodynamic functions -- 1.2 Energy -- 1.2.1 Principles: definition, types, examples, and mathematic statement -- 1.2.2 Energy and chemical reactions: spontaneity, equilibrium, and estimation -- 1.3 Ideal gas -- 1.3.1 Definition -- 1.3.2 Properties -- 1.3.3 Avogadro's law -- 1.3.4 Boyle's law -- 1.3.5 Charles' law -- 1.3.6 Ideal gas law -- 1.4 State function -- 1.4.1 Principles: definition, examples, and significant -- 1.4.2 Mathematics: exact/inexact differentials and Euler's criterion for exactness -- 1.5 The kinetic theory for gases: assumption, definition, derivation, and temperature change -- 1.6 Real gas: properties and equations -- 1.6.1 Compression factor and virial coefficient -- 1.6.2 van der Waals equation -- 1.6.3 Principle of corresponding states -- 1.6.4 Reduced variables -- 1.7 Total and partial derivative expressions of temperature, pressure, and volume: expression for the finite change of thermody ... -- 1.7.1 Partial derivative expressions of temperature, pressure, and volume: expressions for the finite change of thermodynamic mai ... -- 1.8 Thermal equilibrium and zero law of thermodynamics -- 1.9 Summary of the chapter equations -- 2 -- Work, heat, internal energy, and enthalpy -- Introduction -- 2.1 The first law of thermodynamics: principles -- 2.1.1 Energy change: definition -- 2.1.2 Mathematic statement -- 2.2 First case: isothermal expansion of perfect gas -- 2.2.1 Into vacuum -- 2.2.2 Against constant pressure (irreversible).
2.12 Summary of the chapter equations -- 3 -- Entropy: the second and third laws of thermodynamics -- Introduction -- 3.1 The second law of thermodynamics -- 3.1.1 Definition -- 3.1.2 Stability -- 3.1.3 Thermodynamic stability -- 3.1.4 Kinetic stability -- 3.2 Entropy -- 3.2.1 Definition -- 3.2.2 Entropy and thermodynamic parameters -- 3.2.3 Principle of Clausius -- 3.3 Carnot cycle -- 3.3.1 Reversible cycle -- 3.3.2 The network: estimation -- 3.3.3 Efficiency: definition and estimation -- 3.3.4 Kelvin scale and absolute zero -- 3.3.5 Reversible versus irreversible cycle -- 3.4 Entropy basics -- 3.4.1 Entropy equation -- 3.4.2 Entropy and spontaneity -- 3.4.3 Statement of the second law -- 3.5 Calculating the entropy change -- 3.5.1 First case: a change of state at constant temperature -- 3.5.2 Second case: a perfect gas changing volume at constant temperature -- 3.5.3 Third case: a substance being heated or cooled over temperature range -- 3.5.4 Fourth case: an ideal gas undergoing an adiabatic irreversible expansion -- 3.5.5 Entropy change for a chemical reaction -- 3.5.6 Entropy and probability -- 3.5.7 The third law of thermodynamics and absolute entropy -- 3.5.8 Absolute entropy equation -- 3.5.9 Entropy of mixing -- 3.6 Entropy and internal energy relationships -- 3.6.1 Entropy versus internal energy and volume as independent variables, fundamental equation -- 3.6.2 Entropy and internal energy at constant volume -- 3.6.3 Entropy and volume at constant internal energy -- 3.6.4 Internal energy and volume at constant entropy -- 3.7 Entropy and enthalpy relationships -- 3.7.1 Entropy versus enthalpy and pressure as independent variables, fundamental equation -- 3.7.2 Entropy and enthalpy at constant pressure -- 3.7.3 Enthalpy and pressure at constant entropy -- 3.8 Entropy, temperature, pressure, and volume.
3.8.1 Entropy versus temperature and volume as independent variables, fundamental equation -- 3.8.2 Entropy and temperature at constant volume -- 3.8.3 Entropy and volume at constant temperature -- 3.8.4 Entropy versus temperature and volume as independent variables -- 3.8.5 Entropy versus temperature and pressure as independent variables -- 3.8.6 Relations involving entropy -- 3.8.7 Total and partial derivative expressions -- 3.8.8 Entropy and temperature at constant pressure -- 3.8.9 Entropy and volume at constant pressure -- 3.8.10 Entropy and temperature at constant volume -- 3.8.11 Entropy versus temperature and volume as independent variables: fundamental equation -- 3.8.12 Maxwell relations -- 3.9 Summary of the chapter equations -- 4 -- Free energy of pure substance in single phase -- Introduction -- 4.1 Free energy: principles -- 4.1.1 Definition -- 4.1.2 Defining equations -- 4.2 Gibbs energy and total entropy: equations and conditions -- 4.3 Gibbs energy and reversibility -- 4.4 The basic equations for free energy -- 4.4.1 Gibbs energy taking pressure and temperature as independent variables -- 4.4.2 Helmholtz energy taking volume and temperature as independent variables -- 4.5 Equilibrium conditions -- 4.5.1 Constant entropy and volume -- 4.5.2 Constant entropy and pressure -- 4.5.3 Constant pressure and temperature -- 4.6 Free energy and maximum expansion work -- 4.7 Isothermal free energy change -- 4.7.1 Ideal gases, liquid, and solid -- 4.7.2 Chemical reactions -- 4.7.3 Chemical activity: fundamental equation -- 4.8 Relations involving free energy: total and partial derivative expressions -- 4.8.1 Gibbs change taking pressure and temperature as independent variables -- 4.8.2 Helmholtz change taking volume and temperature as independent variables -- 4.8.3 Maxwell relations -- 4.8.4 Internal pressure -- 4.8.5 Internal energy.
4.8.6 Enthalpy -- 4.8.7 Entropy -- 4.9 Free energy, temperature, pressure, and volume -- 4.9.1 Free energy and pressure at constant temperature -- 4.9.2 Free energy and volume at constant temperature -- 4.9.3 Free energy taking pressure and volume as independent variable -- 4.9.4 Free energy and temperature at constant pressure -- 4.9.5 Free energy and volume at constant pressure -- 4.9.6 Free energy taking volume and temperature as independent variable -- 4.9.7 Free energy and pressure at constant volume -- 4.9.8 Free energy and temperature at constant volume -- 4.9.9 Gibbs energy change taking pressure and temperature as independent variable -- 4.9.10 Isothermal Gibbs energy change with pressure -- 4.9.11 Isothermal Gibbs energy change with volume changes -- 4.9.12 Helmholtz energy with temperature at constant volume -- 4.9.13 Helmholtz energy versus the change of volume at constant temperature -- 4.9.14 Enthalpy-entropy parallel behavior at constant temperature and pressure -- 4.10 Chemical potential -- 4.10.1 Definition -- 4.10.2 Chemical potential change at constant temperature -- 4.10.3 Chemical potential change at constant pressure -- 4.10.4 Chemical potential and fugacity -- 4.10.5 Real and standard state -- 4.10.6 Thermodynamic quantities and fugacity coefficient -- 4.10.7 Thermodynamic quantities and virial coefficient -- 4.11 Summary of the chapter equations -- 5 -- Thermodynamics of homogeneous and heterogeneous systems -- Introduction -- 5.1 Variables for open homogeneous system: principles -- 5.2 Chemical potential and thermodynamics functions: basic equation -- 5.3 Meaning of the chemical potential -- 5.4 Partial molar quantities: definition -- 5.5 Equilibrium conditions in open systems: applications -- 5.6 Chemical potential and mole fraction: fundamental equation.
Subject Thermodynamics.
Chemical equilibrium.
Chemical reactions.
Statistical thermodynamics.
Thermodynamique.
Équilibre chimique.
Thermodynamique statistique.
thermodynamics.
Chemical equilibrium
Chemical reactions
Statistical thermodynamics
Thermodynamics
Added Author Addison, Anthony W.
Other Form: Print version: Stephanos, Joseph J. Chemical Thermodynamics and Statistical Aspects San Diego : Elsevier,c2023 9780443152955
ISBN 9780443152962 electronic book
0443152969 electronic book
9780443152955
0443152950
Standard No. AU@ 000074837754

 
    
Available items only