| Description |
1 online resource : illustrations |
|
text txt rdacontent |
|
computer c rdamedia |
|
online resource cr rdacarrier |
| Bibliography |
Includes bibliographical references and index. |
| Note |
Online resource; title from PDF title page (EBSCO, viewed May 25, 2018). |
| Summary |
Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metalsïŽto produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. |
| Contents |
Front Cover; Advances in Transition-Metal Mediated Heterocyclic Synthesis; Copyright Page; Contents; List of Contributors; Foreword; 1 Metal-Mediated Synthesis of Nonaromatic Oxacycles From Allenols; 1.1 Introduction; 1.2 Silver-Catalyzed Reactions; 1.3 Gold-Catalyzed Reactions; 1.4 Platinum-Catalyzed Reactions; 1.5 Palladium-Catalyzed Reactions; 1.6 Lanthanum-Catalyzed Reactions; 1.7 Gallium-Catalyzed Reactions; 1.8 Conclusion; References; 2 Intramolecular Diamination of Alkenes; 2.1 Introduction. |
|
2.2 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intramolecular Vicinal Diamination of Alkenes2.2.1 Palladium Catalysis; 2.2.2 Other Metal Catalysis Using Iodine(III) Oxidants; 2.2.3 Copper Catalysis; 2.3 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intra-/Intermolecular Vicinal Diamination of Alkenes; 2.3.1 Palladium Catalysis; 2.3.2 Copper Catalysis; 2.4 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intermolecular Vicinal Diamination of Alkenes; 2.5 Summary and Outlook; References. |
|
3.2.2.2 With Halides Together With Nucleophilic Partners3.2.2.3 With Halides Together With Electrophilic Partners; 3.2.2.4 With Halides Together With Alkenes and Imines; 3.2.2.5 With Halides Together With Alkynes and Arynes; 3.2.2.6 With Other Substrates; 3.3 Palladium-Catalyzed Carbonylation Processes Leading to Heterocycles Without Incorporation of CO into the Cycle; 3.3.1 Under Oxidative Conditions; 3.3.1.1 Through Carbonylative Carbocyclization; 3.3.1.2 Through Heterocyclization-Alkoxycarbonylation; 3.3.1.3 Through Heterocyclization-Carbonylation-Cyclization Coupling. |
|
3.3.1.4 Through Monocarbonylation of Terminal Alkynes Followed by Intramolecular Conjugate Addition3.3.2 Under Nonoxidative Conditions; 3.3.2.1 With Halides; 3.3.2.2 With Imine Derivatives; 3.3.2.3 With Functionalized Alkynes; 3.4 Conclusions and Perspectives; References; 4 Synthesis of Heterocyclic Compounds Based on Transition-Metal-Catalyzed Carbene Coupling Reactions; 4.1 Introduction; 4.2 Cyclization Prior to Metal Carbene Formation; 4.3 Cyclization Through Other Carbene Precursors; 4.4 Cyclization Through Reductive Elimination; 4.5 Cyclization Through Nucleophilic Displacement. |
| Subject |
Heterocyclic compounds.
|
|
Transition metals.
|
|
Transition metal catalysts.
|
|
Heterocyclic Compounds |
|
Composés hétérocycliques.
|
|
Métaux de transition.
|
|
Catalyseurs à base de métaux de transition.
|
|
SCIENCE -- Chemistry -- Organic.
|
|
Heterocyclic compounds
|
|
Transition metal catalysts
|
|
Transition metals
|
| Added Author |
Solé, Daniel, editor.
|
|
Fernández, Israel, editor.
|
| Other Form: |
Print version: Advances in Transition-Metal Mediated Heterocyclic Synthesis. London : Academic Press, An imprint of Elsevier, [2018] 012811651X 9780128116517 (OCoLC)1011519523 |
| ISBN |
9780128116524 (electronic bk.) |
|
0128116528 (electronic bk.) |
|
9780128116517 |
|
012811651X |
| Standard No. |
AU@ 000062895085 |
|
UKMGB 018880091 |
|
AU@ 000063798557 |
|
