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1 online resource |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
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CIP data; resource not viewed. |
| Contents |
Front Cover; Organosilicon Compounds; Copyright Page; Contents; List of Contributors; About the Editor; Preface; I. Physico-Chemical Studies; 1 X-Ray Crystallography of Organosilicon Compounds (Electron Density and Chemical Bonding in Organosilicon Compounds); 1.1 Introduction; 1.1.1 Multipole Model; 1.1.2 Further Models; 1.1.3 Extracting Bonding Features From the EDD; 1.2 The Nature of the Si-X Bond; 1.3 Aromaticity in Silicon-Containing Compounds; 1.3.1 Three-Membered Rings; 1.3.2 Four-Membered Rings; 1.3.3 Five-Membered Rings; 1.3.4 Six-Membered Rings |
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1.4 Multiple Bonds and Low-Valent Silicon1.4.1 Multiple Bonds; 1.4.2 Silylenes; 1.4.3 Silaallenes and Silylones; 1.5 Conclusions; References; Further Reading; 2 29Si NMR Spectroscopy; Abbreviations; 2.1 General Aspects and Chemical Shifts; 2.2 Special Considerations; 2.2.1 Referencing of the 29Si NMR Chemical Shifts; 2.2.2 29Si NMR Pulse Techniques; 2.2.3 Coupling Constants; 2.3 Conclusions; References; 3 Thermochemistry of Organosilicon Compounds; Abbreviations; 3.1 Introduction; 3.2 Compounds of Tetravalent Silicon; 3.2.1 SiX4 Compounds; 3.2.2 SiXnY4−n Compounds; 3.2.2.1 Halides |
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3.2.2.2 Methylsilanes and methyl silicon halides3.2.3 Organosilanes (Si/C/H); 3.2.4 Oxygen-Containing Compounds (Si/C/H/O); 3.2.5 Nitrogen-Containing Compounds (Si/C/H/N); 3.2.6 Di- and Trisilicon-Containing Compounds; 3.2.7 Other Organosilicon Compounds; 3.3 Bond Dissociation Enthalpies and Free Radicals; 3.3.1 General Comments; 3.3.2 Directly Measured Values; 3.3.3 Derived Bond Dissociation Enthalpies; 3.4 Other Silicon-Containing Species; 3.4.1 Silylenes; 3.4.1.1 SiX2 molecules; 3.4.1.2 SiHX molecules; 3.4.2 [pi]-Bonded Species; 3.5 Appendix; 3.6 Conclusion; References |
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4 UV-Photoelectron Spectroscopy of Organosilicon Compounds4.1 Introduction; 4.2 Ultraviolet-Photoelectron Spectroscopy Instrument for Gas Phase Characterization; 4.2.1 Theoretical Background; 4.2.2 Description of Apparatus; 4.2.2.1 Classical ultraviolet-photoelectron spectroscopy (simple characterization); 4.2.2.2 Improvements; 4.2.2.3 Ultraviolet-photoelectron spectroscopy/mass spectrometry tandem (double characterization); 4.2.3 Coupling Ultraviolet-Photoelectron Spectroscopy Characterization with Synthesis Methods; 4.2.3.1 Flash vacuum thermolysis/ultraviolet-photoelectron spectroscopy |
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4.2.3.2 Vacuum gas solid reaction/ultraviolet-photoelectron spectroscopy4.2.3.3 Gas phase reaction/ultraviolet-photoelectron spectroscopy; 4.2.3.4 Photolysis/ultraviolet-photoelectron spectroscopy; 4.3 Theoretical Methods for Ionization Energy Calculation; 4.3.1 Hartree-Fock-Koopmans' Theorem; 4.3.2 Density Functional Theory-Janak's Theorem; 4.3.3 [delta]SCF (HF or KS) Methods; 4.3.4 Electron Perturbation Theory-Outer Valence Green's Function and P3 Methods; 4.3.5 Post-Hartree-Fock and Related Methods; 4.3.6 Time-Dependent Density Functional Theory; 4.3.7 Corrected Methods |
| Summary |
Annotation This volume contains two parts. In its first part, Experiment (Physico-Chemical Studies), the application of modern instrumental tools (such as X-ray crystallography, 29Si NMR spectroscopy, UV-Photoelectron Spectroscopy, and other methods) for assessing the structures of organosilicon compounds is described. The second part, Applications, reviews the current research in the field of material science, specifically the use of organosilicon compounds in synthetic chemistry directed towards the creation of new materials. |
| Subject |
Organosilicon compounds.
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Organosilicon compounds -- Laboratory manuals.
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Composés organosiliciés.
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Composés organosiliciés -- Manuels de laboratoire.
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SCIENCE -- Chemistry -- Organic.
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Organosilicon compounds
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| Genre/Form |
Electronic books.
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Laboratory Manual |
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Laboratory manuals
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Laboratory manuals.
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Manuels de laboratoire.
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| Other Form: |
Print version : 9780128142134 |
| ISBN |
9780128142141 (ePub ebook) |
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0128142146 (ePub ebook) |
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0128142138 |
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9780128142134 |
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9780128142134 (pbk.) |
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0128142138 |
| Standard No. |
9780128142134 |
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AU@ 000060949204 |
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AU@ 000061154652 |
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GBVCP 1002872693 |
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