| Description |
1 online resource (xii, 572 pages) : illustrations |
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text txt rdacontent |
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computer c rdamedia |
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online resource cr rdacarrier |
| Series |
Studies in surface science and catalysis ; vol. 97 |
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Studies in surface science and catalysis ; 97.
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| Summary |
Formerly, the catalytic use of zeolites was exclusive to the field of acid catalysis. Nowadays, zeolites also find applications as catalysts in a wide array of chemical reactions such as; base catalyzed reactions, Redox reactions and catalytic reactions on transition metals and their complexes in confined environments. The concepts of Brønsted or Lewis acid-base pairs are adequately illustrated in the literature and well-understood in terms of structural and electronic properties of zeolites. By contrast, properties of chemically modified silicates, aluminosilicates and aluminophosphates have not yet been fully explored. The list of oxydo-reduction reactions performed in the presence of these new materials is growing as demonstrated by the selective catalytic reduction of nitrogen oxides or the numerous oxidations employing hydrogen peroxide. Much effort is currently being made to get a better insight into the nature of the sites involved. The zeolite lattice may also be used as a host for encapsulated complexes or metallic clusters allowing the control of nuclearity of these active species and the steric constraints imposed on the reactants. Molecular sieve and shape selectivity effects have also constituted fascinating aspects of zeolite properties. Recent developments leading to increasingly large pore sizes with VPI-5, cloverite and more recently mesoporous molecular sieves have broadened the spectrum of these applications. Indeed, larger and larger reactant and product molecules can be accommodated in these lattices. These new adsorbant/adsorbate systems create additional needs for experimental data and theoretical descriptions of transport properties, in particular of mono- and multi-components diffusion coefficients in the zeolite pore lattice. All these themes, representing the forefront and current trends in zeolite research, were discussed in the submitted papers to the symposium and are widely represented in the selected papers contained in this volume. A feature common to most of these contributions is the combined use of a variety of analytical techniques. Some of these techniques are at the frontier of the latest analytical developments such as multiple scattering EXAFS and bidimensional MAS-NMR. |
| Bibliography |
Includes bibliographical references and indexes. |
| Note |
Print version record. |
| Contents |
Front Cover; Zeolites: A Refined Tool For Designing Catalytic Sites; Copyright Page; Contents; Foreword; Acknowledgements; Chapter 1. One and Two-Dimensional Solid-State NMR Investigations of the Three-Dimensional Structures of Zeolite-Organic Sorbate Complexes; Chapter 2. The Use of Small, Weakly Basic Probe Molecules for the Investigation of Brønsted Acid Sites in Zeolites by NMR Spectroscopy; Chapter 3. Determination of the Environment of Titanium Atoms in TS-1 Silicalite by Ti K-edge X-ray Absorption Spectroscopy, 29Si and 1H Nuclear Magnetic Resonance. |
| Access |
Use copy Restrictions unspecified star MiAaHDL |
| Reproduction |
Electronic reproduction. [Place of publication not identified] : HathiTrust Digital Library, 2010. MiAaHDL |
| System Details |
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. http://purl.oclc.org/DLF/benchrepro0212 MiAaHDL |
| Processing Action |
digitized 2010 HathiTrust Digital Library committed to preserve pda MiAaHDL |
| Language |
English. |
| Subject |
Zeolites -- Congresses.
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Zéolites -- Congrès.
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NATURE -- Rocks & Minerals.
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SCIENCE -- Earth Sciences -- Mineralogy.
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Zeolites
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Elementos de transicao.
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Mineralogia.
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| Indexed Term |
Zeolites |
| Genre/Form |
Congress |
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proceedings (reports)
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Conference papers and proceedings
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Conference papers and proceedings.
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Actes de congrès.
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| Added Author |
Bonneviot, Laurent.
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Kaliaguine, S., 1940-
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| Other Form: |
Print version: International Zeolite Symposium (1995 : Québec, Québec). Zeolites. Amsterdam ; New York : Elsevier, 1995 0444821309 9780444821300 (DLC) 95221621 (OCoLC)33330074 |
| ISBN |
9780444821300 |
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0444821309 |
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9780080544694 (electronic bk.) |
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008054469X (electronic bk.) |
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1281984728 |
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9781281984722 |
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9786611984724 |
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6611984720 |
| Standard No. |
AU@ 000056736337 |
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CHNEW 001005905 |
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DEBBG BV039827972 |
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DEBBG BV042304376 |
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DEBSZ 40530370X |
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DEBSZ 482353309 |
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GBVCP 878886214 |
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NZ1 12433052 |
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NZ1 15188442 |
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